3,5,7-Tripropyl-1-azaadamantane-4,6,10-triol
نویسندگان
چکیده
The title compound, C(18)H(33)NO(3), was prepared according to a highly diastereoselective hydrogenation procedure from 3,5,7-triallyl-1-aza-adamantane-4,6,10-trione. The crystal structure of the title compound contains two crystallographically independent mol-ecules (Z' = 2), which are linked by inter-molecular hydrogen bonding into chains. In contrast to the aza-adamantanones, the aza-adamantanetriol core of the title compound does not show any particular C-C bond elongation.
منابع مشابه
Tripropylammonium trithiocyanurate
IN THE TITLE COMPOUND (SYSTEMATIC NAME tripropyl-azanium 2,4,6-tris-ulfanyl-idene-cyclo-hexan-1-ide), (C(3)H(7))(3)HN(+)·C(3)H(2)N(3)S(3) (-), one H atom of trithio-cyanuric acid is accepted by tripropyl-amine to form the ammonium ion. Coplanar trithio-cyanurate and tripropyl-ammonium ions [dihedral angle = 82.33 (8)°] form the salt, which is stabilised by various N-H⋯S and N-H⋯N contacts.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008